Ceramic Matrix Composites (CMCs) represent a transformative breakthrough in materials science, addressing the growing demand for high-performance materials in extreme environments. These composites retain the thermal stability, corrosion resistance, and mechanical strength of ceramics while overcoming their inherent brittleness through composite engineering.
CMCs are increasingly utilized in aerospace, energy, medicine, and electronics, where lightweight structures, high-temperature resistance, and mechanical durability are essential.
To fully unlock their potential, precise control over the matrix composition is crucial. In fact, for optimal performance, the matrix must ensure:
✔ Excellent dispersion of ceramic particles in the slurry
✔ High solid loading with low viscosity for better infiltration
✔ Compatibility with additives to tailor performance
✔ High reactivity for efficient consolidation
✔ Controlled porosity to enhance mechanical properties
1. Ox/Ox CMCs: Performance and Challenges
Ox/Ox CMCs are typically composed of alumina or mullite fibers embedded in an oxide matrix. These fibers enhance strength, toughness, and thermal resistance, while the matrix plays a key role in load transfer, fiber protection, and crack deflection. Studies show that an optimal matrix porosity of around 30% is ideal for balancing mechanical strength and thermal performance.
Several challenges must be addressed to achieve such Ox/Ox CMC performance, including:
✔ Mechanical Degradation of ceramic fibers at High Temperatures
✔ Grain Growth Leading to Reduced Mechanical Strength
✔ The Need for Low-Temperature Sintering to Preserve Fiber Integrity
However, achieving this requires precise control over particle size distribution, doping levels, and viscosity. This is where Baikowski®’s SLAz slurry comes into play, offering an advanced high-purity alumina and nano-zirconia solution that meets these critical parameters.
2. SLAz: The Key to Next-Generation Ceramic Matrix Composites
SLAz is Baikowski®’s high-purity α-alumina slurry, doped with a customized ratio of zilight® nano-zirconia, the smallest nano-zirconia on the market, developed by Mathym®, a Baikowski® Group company. The SLAz range includes a doping level of nano zirconia up to 28 wt%, a solid loading of slurries up to 60 wt%, low viscosity, and a large pH range, that enable:
1- Controlled Grain Growth & Microstructure Stability
Mathym’s nano-zirconia effectively limits excessive alumina grain growth, helping to preserve the mechanical integrity of the matrix. Additionally, its uniform dispersion ensures consistent microstructural performance throughout the composite, leading to enhanced reliability and durability.
2- Enhanced Processability & Stability
SLAz remains stable across a wide pH range (4–10), ensuring long-term slurry stability during processing and optimizing manufacturability. SLAz grace à la réactivé au frittage, elle se consolide à basse température ce qui permet de ne pas endommager les fibres.
3- Enhanced Fiber Protection & Mechanical Properties
SLAz could reinforces the alumina matrix, making it an ideal solution for high-performance applications in extreme environments.
3. SLAz Slurry Characterization
Baikowski® has rigorously engineered SLAz to meet high-performance standards such as:
✔ Low Viscosity – Ensures easy processing and fiber infiltration.
✔ Zeta Potential Optimization – Provides a stable suspension with a wide pH range.
✔ Controlled Doping Levels – Up to 28% nano-zirconia, ensuring fine microstructure control.
✔ Tailored Solid Loading – Up to 60 wt% for high-density matrix formation.
✔ Homogeneous Dispersion – Guarantees uniform properties after sintering.
Viscosity
- No significant change for 7 wt% zilight loading
- Slight increase in viscosity from 14wt% Zilight loading
- Viscosity remains low (below 0.3 Pa.s)
Zeta potential curves
Zeta potential curves of SLA-z and pure zilight dispersion are similar:
- High SSA
- Higher dispersant amount in Zilight dispersion
- Zilight tends to form a layer on alumina grain surface
3. Ceramics characterization SLA-z
Densification occurs at higher temperature with zilight doping and Homogeneous dispersion limits grain growth.
If Baikowski® continues to push the boundaries of high-performance Ox/Ox CMC solutions with SLAz, the innovation doesn’t stop there.
For more information on Baikowski’s CMC solutions, download your leaflet and do not hesitate to contact our team.
SLAz SLURRIES
for CMC applications
Download the SLAz leafletRecognizing the growing demand for mullite-based CMCs, Baikowski® has developed SLMz, a tailor-made mullite slurry doped with zilight® nano-zirconia : SLMz.
Early results show promising effects similar to SLAz, including a comparable impact on zeta potential, an IEP downshift dependent on zilight® loading, and a significant decrease in viscosity.